Annealing effect on the photoelectrochemical and photocatalytic performance of TiO2 nanorod arrays

Abstract

TiO₂ nanorod arrays (NRAs) with 540 nm length and an amorphous porous structure, were fabricated by oblique angle deposition method. The as-prepared amorphous TiO₂ NRAs transform gradually into anatase phase after annealing with a temperature higher than 350 °C, whereas the specific surface area decreases due to the better crystallinity. The intensity of hydroxyl groups increases with enhancing annealing temperature, then decreases above 450 °C. The photocatalytic and photo-conversion properties benefit from the high crystallinity of TiO₂ NRAs and high density of hydroxyl groups on the surface. It shows that TiO₂ NRAs annealed at 450 °C exhibit the highest photoconversion efficiency and maximum degradation rate of MO, which can be ascribed to the excellent crystallization and the optimum density of hydroxyl groups on the surface of TiO₂. The TiO₂ NRAs with enhanced crystallinity and fine structures are very promising for photocatalyst materials for environmental protection.