1,3-Dipolar [3 + 3] cycloaddition of α-halohydroxamate-based azaoxyallyl cations with hydrazonoyl chloride-derived nitrile imines

Hong-Wu Zhao; Yu-Di Zhao; Yue-Yang Liu; Li-Jiao Zhao; Xiu-Qing Song; Xiao-Qin Chen; Hai-Liang Pang; Juan Du; Ning-Ning Feng

doi:10.1039/C7RA09766B

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1,3-Dipolar [3 + 3] cycloaddition of α-halohydroxamate-based azaoxyallyl cations with hydrazonoyl chloride-derived nitrile imines†

Hong-Wu Zhao,

*^a Yu-Di Zhao,

^a Yue-Yang Liu,

^a Li-Jiao Zhao,

^a Xiu-Qing Song,^a Xiao-Qin Chen,

^a Hai-Liang Pang,

^a Juan Du

^a and Ning-Ning Feng

Author affiliations

* Corresponding authors

^a College of Life Science and Bio-engineering, Beijing University of Technology, No. 100 Pingleyuan, Chaoyang District, Beijing 100124, P. R. China
E-mail: hwzhao@bjut.edu.cn

Abstract

Promoted by Et₃N, the 1,3-dipolar [3 + 3] cycloaddition of α-halohydroxamate-based azaoxyallylcations with hydrazonoyl chloride-derived nitrile imines occurred efficiently, and furnished desired products in acceptable chemical yields. The chemical structure of the title compounds was firmly confirmed by an X-ray single crystal structure analysis.

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DOI: https://doi.org/10.1039/C7RA09766B
Article type: Paper
Submitted: 02 Sep 2017
Accepted: 28 Nov 2017
First published: 05 Dec 2017
This article is Open Access

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RSC Adv., 2017,7, 55106-55109

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1,3-Dipolar [3 + 3] cycloaddition of α-halohydroxamate-based azaoxyallyl cations with hydrazonoyl chloride-derived nitrile imines

H. Zhao, Y. Zhao, Y. Liu, L. Zhao, X. Song, X. Chen, H. Pang, J. Du and N. Feng, RSC Adv., 2017, 7, 55106 DOI: 10.1039/C7RA09766B

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1,3-Dipolar [3 + 3] cycloaddition of α-halohydroxamate-based azaoxyallyl cations with hydrazonoyl chloride-derived nitrile imines†

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1,3-Dipolar [3 + 3] cycloaddition of α-halohydroxamate-based azaoxyallyl cations with hydrazonoyl chloride-derived nitrile imines

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