Qualitative and quantitative analysis of fatty acid profiles of Chinese pecans (Carya cathayensis) during storage using an electronic nose combined with chemometric methods

Abstract

Chinese pecans (Carya cathayensis) continuously deteriorate during storage because of their high fatty acid contents. In this study, an electronic nose (E-nose) was introduced to characterize Chinese pecans with different storage times. Chemometric methods (principal component analysis (PCA), partial least squares regression (PLSR), and back propagation neural networks (BPNNs)) were employed to analyze E-nose data. For qualitative analysis, PCA could visualize the discrimination between different pecans based on the E-nose data. For quantitative analysis, the results indicated that BPNN models performed better both in predicting storage times and fatty acid contents than the PLSR models. In addition, a multi-target BPNN regression model was built to simultaneously predict the contents of the six main fatty acids, and the results (R² > 0.95 in calibration sets and R² > 0.88 in validation sets) were satisfactory. This study provides a potentially viable method for determining the storage times and fatty acid profiles of nut products.