Hollow mesoporous silica supported PtIr bimetal catalysts for selective hydrogenation of phenol: significant promotion effect of iridium

Abstract

Selective hydrogenation of phenol is of great significant for the production of Nylon 6. Herein, highly efficient and stable Ir promoted Pt catalysts for the hydrogenation of phenol are prepared by deposition of Pt–Ir nanoparticles onto hollow mesoporous silica spheres (HMSs) through a facile wet-impregnation and H₂ reduction method. The obtained PtIr/HMS catalyst with Ir/Pt molar ratio of 0.1 shows a highest hydrogenation rate of 4255 mmol h⁻¹ g_Pt⁻¹ with cyclohexanone selectivity of 85% at 50 °C and 0.5 MPa of p_H2, which is 3 times and 8.6 times higher than that of the mono Pt/HMS catalyst and commercial Pt catalyst, respectively. The trace addition of Ir promoter essentially contributes to the enhanced hydrogenation activity by improving the metal dispersion of Pt nanoparticles and promoting the charge transfer between the Pt and Ir. This work provides an effective protocol in developing high performance catalysts for phenol hydrogenation under mild reaction conditions.