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Issue 59, 2017, Issue in Progress
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Protic salt-based nitrogen-doped mesoporous carbon for simultaneous electrochemical detection of Cd(II) and Pb(II)

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Abstract

Nitrogen-doped mesoporous carbon (NMC) derived from a single small-molecule protic salt (p-phenylenediamine bisulfate) is used for sensing toxic heavy metal ions. Using Nafion, bismuth and NMC to anchor the glassy carbon electrode surface, the fabricate electrode shows high sensitivity for detecting Cd(II) and Pb(II). The limits of detection (S/N = 3) are estimated to be 0.3 μg L−1 for Cd(II) and 0.4 μg L−1 for Pb(II), respectively, which are 10 and 25 times lower than the maximum acceptable content for drinking water recommended by the WHO. Furthermore, the sensor is successfully used to analyze Cd(II) and Pb(II) in tap-water with high anti-interference capability and good recovery.

Graphical abstract: Protic salt-based nitrogen-doped mesoporous carbon for simultaneous electrochemical detection of Cd(ii) and Pb(ii)

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Publication details

The article was received on 28 Apr 2017, accepted on 15 Jul 2017 and first published on 25 Jul 2017


Article type: Paper
DOI: 10.1039/C7RA04806H
Citation: RSC Adv., 2017,7, 36929-36934
  • Open access: Creative Commons BY-NC license
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    Protic salt-based nitrogen-doped mesoporous carbon for simultaneous electrochemical detection of Cd(II) and Pb(II)

    D. Qin, R. Xu, H. Shen, X. Mamat, L. Wang, S. Gao, Y. Wang, N. Yalikun, T. Wagberg, S. Zhang, Q. yuan, Y. Li and G. Hu, RSC Adv., 2017, 7, 36929
    DOI: 10.1039/C7RA04806H

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