Boosting visible light photo-/Fenton-catalytic synergetic activity of BiOIO3 by coupling with Fe2O3

Abstract

The combination of a semiconductor photocatalyst with guest transition metal oxides can extend its light absorption property in the visible region, leading to the emergence of potential catalysts for solar photocatalytic degradation. In the present study, Fe₂O₃/BiOIO₃ nanosheets with heterojunction couples have been fabricated in one-step by a simple hydrothermal method and used as a heterogeneous Fenton-like photocatalyst for the oxidative degradation of p-nitrophenol (PNP) under visible light. The absorption range of BiOIO₃ extended to the visible light region with the introduction of Fe, while the band gap is dramatically decreased from 3.00 eV for pure BiOIO₃ to 1.81 eV for 30% Fe₂O₃/BiOIO₃. The recombination of photogenerated electron–hole pairs can also be prevented effectively. The intrinsic relationship between structure and catalytic activity was fully studied and a possible catalytic mechanism was proposed. The enhanced photocatalytic activity can be attributed to the synergistic effect of heterojunction semiconductor photocatalysis and heterogeneous Fenton catalysis caused by BiOIO₃ and Fe₂O₃. This highly active heterogeneous catalyst has the potential for efficient utilization of solar energy in the visible range and can be applied in environmental remediation and waste water treatment.