Jump to main content
Jump to site search

Issue 32, 2017, Issue in Progress
Previous Article Next Article

A solar cell for maximizing voltage up to the level difference of two photocatalysts: optimization and clarification of the electron pathway

Author affiliations

Abstract

Fuel cells (FCs) and solar cells (SCs) are indispensable devices for a hydrogen energy society. The voltages obtained are less than 1 V per cell for most FCs and SCs. Herein, we use a recently developed SC comprising two photocatalysts. In principle, both TiO2 and BiOCl are photo-excited, and the energy difference between the conduction band (CB) minimum of TiO2 for excited electrons (−0.11 V) and the valence band (VB) maximum of BiOCl for holes (2.64 V) can provide a theoretical electromotive force of 2.75 V. This SC converts light energy into an electromotive force corresponding to the level difference of the two photocatalysts permanently mediated by the redox of water/O2. The diffusion overpotential of electrons in the photocatalysts (0.23–0.41 V) and the leakage current (0.38 V) are experimentally evaluated. The contact between the TiO2 film and ITO layer is improved by the better dispersion of the TiO2 suspension at a lower pH than that of the isoelectric point. Cyclic voltammetry data suggest the formation of O/Cl vacancy sites during the SC tests and the superiority of the rear orientation of the BiOCl photocatalyst on the cathode and effective photo-oxidation of water over TiO2, whereas impedance measurements suggest a smaller impedance for the tight and uniform TiO2 film in comparison to the porous BiOCl film. Thus, in the optimized configuration of the electrodes (irradiation from the other side of the photocatalyst), the leakage current and the diffusion overpotential in the catalyst layers are effectively suppressed to realize an open-circuit voltage of 1.91 V and cell output of 55.8 µW per 1.3 cm2.

Graphical abstract: A solar cell for maximizing voltage up to the level difference of two photocatalysts: optimization and clarification of the electron pathway

Back to tab navigation

Article information


Submitted
02 Mar 2017
Accepted
21 Mar 2017
First published
05 Apr 2017

This article is Open Access

RSC Adv., 2017,7, 19996-20006
Article type
Paper

A solar cell for maximizing voltage up to the level difference of two photocatalysts: optimization and clarification of the electron pathway

M. Yoshiba, Y. Ogura, M. Tamba, T. Kojima and Y. Izumi, RSC Adv., 2017, 7, 19996
DOI: 10.1039/C7RA02600E

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.

Reproduced material should be attributed as follows:

  • For reproduction of material from NJC:
    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
  • For reproduction of material from PCCP:
    [Original citation] - Published by the PCCP Owner Societies.
  • For reproduction of material from PPS:
    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
  • For reproduction of material from all other RSC journals:
    [Original citation] - Published by The Royal Society of Chemistry.

Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.


Social activity

Search articles by author

Spotlight

Advertisements