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Issue 3, 2017, Issue in Progress

Efficient Pd@MIL-101(Cr) hetero-catalysts for 2-butyne-1,4-diol hydrogenation exhibiting high selectivity

Author affiliations

Abstract

Pd@MIL-101(Cr) hetero-catalysts have been successfully prepared using the metal–organic chemical vapour deposition (MOCVD) approach, by choosing [Pd(η3-C3H5)(η5-C5H5)] as a volatile precursor, and the hydrothermally stable metal–organic framework, MIL-101(Cr) as a support. The prepared Pd@MIL-101(Cr) hetero-catalysts characterized with various analytical techniques, exhibited highly monodispersed immobilized Pd nanoparticles in the MIL-101(Cr) cavities, while retaining the pristine crystallinity and porosity. The intact hybrid Pd@MIL-101(Cr) has been demonstrated to be an efficient catalyst for 2-butyne-1,4-diol hydrogenation with excellent activity, stability and selectivity (2-butene-1,4-diol (>94%)).

Graphical abstract: Efficient Pd@MIL-101(Cr) hetero-catalysts for 2-butyne-1,4-diol hydrogenation exhibiting high selectivity

Supplementary files

Article information


Submitted
24 Oct 2016
Accepted
20 Dec 2016
First published
05 Jan 2017

This article is Open Access

RSC Adv., 2017,7, 1626-1633
Article type
Paper

Efficient Pd@MIL-101(Cr) hetero-catalysts for 2-butyne-1,4-diol hydrogenation exhibiting high selectivity

D. Yin, C. Li, H. Ren, O. Shekhah, J. Liu and C. Liang, RSC Adv., 2017, 7, 1626 DOI: 10.1039/C6RA25722D

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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