Issue 2, 2017, Issue in Progress
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RSC Advances

Synthesis of dendrobatid alkaloid (+)-167B and (+)-209D and the investigation of diastereoselectivity using DFT calculations†

Wen-Hua Chiou*a  and  Hao-Yu Chena  

* Corresponding authors

a Department of Chemistry, National Chung Hsing University, Taichung, Taiwan, ROC
E-mail: wchiou@dragon.nchu.edu.tw
Fax: +886-4-22862547
Tel: +886-4-22840411-420

Abstract

The synthesis of dendrobatid alkaloid (+)-167B and (+)-209D has been developed on the basis of the effective preparation of chiral tropinone 7-azabicyclo[3.2.1]octan-6-ol. DFT calculations have been applied to explain the observed diastereoselectivity.

Graphical abstract: Synthesis of dendrobatid alkaloid (+)-167B and (+)-209D and the investigation of diastereoselectivity using DFT calculations

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Article information

DOI
https://doi.org/10.1039/C6RA24960D
Article type
Communication
Submitted
09 Oct 2016
Accepted
20 Oct 2016
First published
03 Jan 2017
This article is Open Access
Creative Commons BY license

RSC Adv., 2017,7, 684-687

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Synthesis of dendrobatid alkaloid (+)-167B and (+)-209D and the investigation of diastereoselectivity using DFT calculations

W. Chiou and H. Chen, RSC Adv., 2017, 7, 684 DOI: 10.1039/C6RA24960D

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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