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Issue 10, 2017
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Iridium-catalyzed intermolecular directed dehydrogenative ortho C–H silylation

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Abstract

An efficient method for iridium-catalyzed direct silylation of C(sp2)–H and C(sp3)–H bonds using HSiMe(OSiMe3)2 as the silylating reagent is described. The reaction is amenable to various directing groups under simple and mild conditions leading to the mono- and regioselective synthesis of versatile organosilane compounds.

Graphical abstract: Iridium-catalyzed intermolecular directed dehydrogenative ortho C–H silylation

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Article information


Submitted
28 Apr 2017
Accepted
27 Jun 2017
First published
28 Jun 2017

Org. Chem. Front., 2017,4, 1943-1946
Article type
Research Article

Iridium-catalyzed intermolecular directed dehydrogenative ortho C–H silylation

H. Wang, G. Wang and P. Li, Org. Chem. Front., 2017, 4, 1943
DOI: 10.1039/C7QO00340D

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