SCHEDULED MAINTENANCE
We report on the use of visible light photoredox catalysis for the radical Smiles rearrangement of 2-aryloxybenzoic acids to obtain aryl salicylates. The method is free of noble metals and operationally simple and the reaction can be run under mild batch or flow conditions. Being a redox neutral process, no stoichiometric oxidants or reductants are needed.
Jose. C. Gonzalez-Gomez, N. P. Ramirez, T. Lana-Villarreal and P. Bonete, Org. Biomol. Chem., 2017, 15, 9680 DOI: 10.1039/C7OB02579C
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