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Issue 19, 2017
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An unprecedented 3D architecture based on a Nb/W mixed-addendum polyoxometalate and lanthanide–organic complex: synthesis, crystal structure and properties

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Abstract

For the first time, an unprecedented 3D framework based on lanthanide-containing Nb/W mixed-addendum polyoxometalate [H3La8(H2O)32(C6H5NO2)6][SiW9Nb3O40]3·8H2O (1) has been obtained by utilizing the steam-assisted conversion method. Meanwhile, the stability, electrochemical behavior, and photoluminescence properties of 1 have also been discussed.

Graphical abstract: An unprecedented 3D architecture based on a Nb/W mixed-addendum polyoxometalate and lanthanide–organic complex: synthesis, crystal structure and properties

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Supplementary files

Article information


Submitted
06 Jun 2017
Accepted
31 Jul 2017
First published
04 Aug 2017

New J. Chem., 2017,41, 10532-10536
Article type
Letter

An unprecedented 3D architecture based on a Nb/W mixed-addendum polyoxometalate and lanthanide–organic complex: synthesis, crystal structure and properties

M. Yang, W. Chen, C. Qin, W. Yao, Y. Yin and Z. Su, New J. Chem., 2017, 41, 10532
DOI: 10.1039/C7NJ02011B

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