Issue 2, 2017
From the journal:

New Journal of Chemistry

A perylene complex with a one-dimensional coordination polymer containing [Mn6O2(CHCl2COO)10(H2O)2] cluster units linked by 3,10-perylenequinone bridges†

Lyudmila A. Kushch,‡a   Anna V. Kazakova, ORCID logo *a   Svetlana A. Mironova,a   Eduard B. Yagubskii,*a   Sergey V. Simonov,b   Leokadiya V. Zorina,b   Rimma P. Shibaeva,*b   Andrey V. Sadakovc  and  Vladimir S. Mironov*d  

* Corresponding authors

a Institute of Problems of Chemical Physics of Russian Academy of Sciences, Semenov's av., 1, Chernogolovka 142432, MD, Russian Federation
E-mail: kazakova@icp.ac.ru, yagubski@icp.ac.ru
Tel: +7-496-52-21185

b Institute of Solid State Physics of Russian Academy of Sciences, Academician Ossipyan str., 2, Chernogolovka 142432, MD, Russian Federation
E-mail: shibaeva@issp.ac.ru

c P. N. Lebedev Physical Institute of Russian Academy of Sciences, Leninskii av., 53, Moscow 119333, Russian Federation

d A.V. Shubnikov Institute of Crystallography of Russian Academy of Sciences, Leninskii av., 59, Moscow 119333, Russian Federation
E-mail: mirsa@list.ru

Abstract

The crystals of a perylene complex with the polymeric cluster containing [Mn6O2(O2CCHCl2)10(H2O)2] units assembled by 3,10-perylenequinone bridges, {[Mn6O2(O2CCHCl2)10(H2O)2(C20H10O2)]2n·(C20H12)n} (I), were obtained in the reaction of [Mn12O12(O2CCHCl2)16(H2O)4] with perylene. Unlike the Mn12 oxodichloroacetate cluster, the reaction of the Mn12 oxobenzoate cluster, [Mn12O12(O2CPh)16(H2O)4], with perylene does not occur. However, it turned out that the crystals isolated from the reaction are a new Mn12 oxobenzoate cluster containing three molecules of coordinated H2O and solvate molecules of hexane, [Mn12O12(O2CC6H5)16(H2O)3]·2C6H12 (II). Crystal structures of complexes I and II as well as the magnetic properties of the former were studied.

Graphical abstract: A perylene complex with a one-dimensional coordination polymer containing [Mn6O2(CHCl2COO)10(H2O)2] cluster units linked by 3,10-perylenequinone bridges

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Article information

DOI
https://doi.org/10.1039/C6NJ03097A
Article type
Paper
Submitted
04 Oct 2016
Accepted
12 Dec 2016
First published
13 Dec 2016

New J. Chem., 2017,41, 793-801

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A perylene complex with a one-dimensional coordination polymer containing [Mn6O2(CHCl2COO)10(H2O)2] cluster units linked by 3,10-perylenequinone bridges

L. A. Kushch, A. V. Kazakova, S. A. Mironova, E. B. Yagubskii, S. V. Simonov, L. V. Zorina, R. P. Shibaeva, A. V. Sadakov and V. S. Mironov, New J. Chem., 2017, 41, 793 DOI: 10.1039/C6NJ03097A

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