Syntheses, structures, and chiroptical and magnetic properties of chiral clusters built from Schiff bases: a novel [MnIIMnIII6NaI2] core

A. Escuer; J. Mayans; M. Font-Bardia; M. Górecki; L. Di Bari

doi:10.1039/C7DT00811B

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Syntheses, structures, and chiroptical and magnetic properties of chiral clusters built from Schiff bases: a novel [Mn^IIMn ^III₆Na ^I₂] core†

A. Escuer,

*^a J. Mayans,

^a M. Font-Bardia,^b M. Górecki^c and L. Di Bari

Author affiliations

* Corresponding authors

^a Departament de Química Inorgànica i Orgànica, Secció Inorgànica and Institute of Nanoscience (IN2UB) and Nanotechnology, Universitat de Barcelona, Av. Diagonal 645, Barcelona-08028, Spain
E-mail: albert.escuer@ub.edu

^b Departament de Mineralogia, Cristal·lografia i Dipòsits Minerals and Unitat de Difracció de R-X. Centre Científic i Tecnològic de la Universitat de Barcelona (CCiTUB). Universitat de Barcelona, Solé i Sabarís 1-3, 08028 Barcelona, Spain

^c Dipartimento di Chimica e Chímica Industriale, Università di Pisa, Via Moruzzi 13, I-56124 Pisa, Italy

Abstract

Chiral clusters with Mn^IIMn^III₃Na^I and the new Mn^IIMn^III₆Na^I₂ cores have been synthesised employing enantiomerically pure Schiff bases and halide ligands. The new compounds have been characterized by electronic circular dichroism (ECD) and magnetic susceptibility.

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Article information

DOI: https://doi.org/10.1039/C7DT00811B
Article type: Communication
Submitted: 06 Mar 2017
Accepted: 03 Apr 2017
First published: 05 Apr 2017

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Dalton Trans., 2017,46, 6514-6517

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Syntheses, structures, and chiroptical and magnetic properties of chiral clusters built from Schiff bases: a novel [Mn^IIMn^III₆Na^I₂] core

A. Escuer, J. Mayans, M. Font-Bardia, M. Górecki and L. Di Bari, Dalton Trans., 2017, 46, 6514 DOI: 10.1039/C7DT00811B

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Dalton Transactions