Issue 31, 2017
From the journal:

Dalton Transactions

Unprecedented ferromagnetic Gd⋯nitronyl nitroxide coupling through a hydrogen bonding bridge†

Juan Sun,a   Meng Yang,a   Zan Sun,a   Xiufeng Wang,a   Yue Maa  and  Licun Li ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry and Tianjin Key Laboratory of Metal and Molecule-based Material Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China
E-mail: llicun@nankai.edu.cn

Abstract

A novel lanthanide(III)–nitronyl nitroxide chain {[Gd(hfac)3(Nit-Ph-3,5-bIm)(H2O)]·C4H10O}n (1) was prepared and characterized. Strikingly, an unexpected ferromagnetic coupling between the Gd(III) ion and the nitroxide group mediated by hydrogen bonding has been observed for the first time.

Graphical abstract: Unprecedented ferromagnetic Gd⋯nitronyl nitroxide coupling through a hydrogen bonding bridge

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Article information

DOI
https://doi.org/10.1039/C7DT02232H
Article type
Communication
Submitted
20 Jun 2017
Accepted
11 Jul 2017
First published
11 Jul 2017

Dalton Trans., 2017,46, 10189-10192

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Unprecedented ferromagnetic Gd⋯nitronyl nitroxide coupling through a hydrogen bonding bridge

J. Sun, M. Yang, Z. Sun, X. Wang, Y. Ma and L. Li, Dalton Trans., 2017, 46, 10189 DOI: 10.1039/C7DT02232H

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