Issue 11, 2017

Highly efficient cold-white light emission in a [Au2CuCl2(P∩N)2]PF6 type salt

Abstract

In the trinuclear, heterometallic cluster compound [Au2CuCl2(P∩N)2]PF6 metallophilic interactions give rise to very efficient cold-white light emission as a result of at least two thermally non-equilibrated emissive triplet states (one of mainly Cu → py and the other of Au → py character, respectively) with exceptional spin–orbit coupling and short emission lifetimes, which are competitive to PtII- and IrIII-based emitters.

Graphical abstract: Highly efficient cold-white light emission in a [Au2CuCl2(P∩N)2]PF6 type salt

Supplementary files

Article information

Article type
Communication
Submitted
16 Jan 2017
Accepted
09 Feb 2017
First published
09 Feb 2017
This article is Open Access
Creative Commons BY license

Dalton Trans., 2017,46, 3438-3442

Highly efficient cold-white light emission in a [Au2CuCl2(P∩N)2]PF6 type salt

E. Hobbollahi, M. List, B. Hupp, F. Mohr, R. J. F. Berger, A. Steffen and U. Monkowius, Dalton Trans., 2017, 46, 3438 DOI: 10.1039/C7DT00180K

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