Jump to main content
Jump to site search

Issue 10, 2017
Previous Article Next Article

Preparation and catalytic performance of a molecularly imprinted Pd complex catalyst for Suzuki cross-coupling reactions

Author affiliations

Abstract

A SiO2-supported molecularly imprinted Pd complex with SiO2-matrix overlayers was prepared as a Suzuki cross-coupling catalyst. A ligand on the supported Pd complex was used as a molecular imprinting template to create the reaction space. The structures of the supported and molecularly imprinted Pd complexes on SiO2 were determined by solid-state MAS 13C, 29Si, and 31P NMR; diffuse reflectance UV/vis; XPS; and Pd K-edge XAFS. The catalytic performance of the molecularly imprinted Pd complex catalyst was very different for various combinations of aryl iodides and arylboronic acids. Reactants with bulky substituent groups were hindered on the imprinted catalyst in Suzuki cross-coupling reactions.

Graphical abstract: Preparation and catalytic performance of a molecularly imprinted Pd complex catalyst for Suzuki cross-coupling reactions

Back to tab navigation

Supplementary files

Publication details

The article was received on 12 Jan 2017, accepted on 26 Jan 2017 and first published on 03 Feb 2017


Article type: Paper
DOI: 10.1039/C7DT00124J
Citation: Dalton Trans., 2017,46, 3125-3134
  •   Request permissions

    Preparation and catalytic performance of a molecularly imprinted Pd complex catalyst for Suzuki cross-coupling reactions

    S. Muratsugu, N. Maity, H. Baba, M. Tasaki and M. Tada, Dalton Trans., 2017, 46, 3125
    DOI: 10.1039/C7DT00124J

Search articles by author

Spotlight

Advertisements