Issue 10, 2017

Dy(iii)-Carboxylate chain containing quasi-D5h sites exhibits enhanced energy barrier for magnetization reversal

Abstract

A slight modification of the coordinating solvent molecule induced a change in the local symmetry at one of the metal sites of a Dy(III)-carboxylate chain complex from quasi-D5h (hepta-coordinated) to C2v (octa-coordinated). This afforded an effective energy barrier for magnetization reversal, which was significantly changed from 403.6 K (diluted) to about 7.5 K.

Graphical abstract: Dy(iii)-Carboxylate chain containing quasi-D5h sites exhibits enhanced energy barrier for magnetization reversal

Supplementary files

Article information

Article type
Communication
Submitted
17 Nov 2016
Accepted
12 Dec 2016
First published
13 Dec 2016

Dalton Trans., 2017,46, 3100-3104

Dy(III)-Carboxylate chain containing quasi-D5h sites exhibits enhanced energy barrier for magnetization reversal

G. Zhou, Y. Ding and Y. Zheng, Dalton Trans., 2017, 46, 3100 DOI: 10.1039/C6DT04366F

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