Issue 4, 2017

The mechanism of activation of amidobenzylidene ruthenium chelates – latent catalysts of olefin metathesis

Abstract

Amidobenzylidene ruthenium chelates – latent catalysts of olefin metathesis can be easily activated by the addition of Brønsted or Lewis acids. Their activation in the presence of hydrogen chloride involves the formation of catalytically active trans-dichloro carbamatobenzylidene ruthenium chelates.

Graphical abstract: The mechanism of activation of amidobenzylidene ruthenium chelates – latent catalysts of olefin metathesis

Supplementary files

Article information

Article type
Paper
Submitted
10 Nov 2016
Accepted
23 Dec 2016
First published
09 Jan 2017

Dalton Trans., 2017,46, 1277-1282

The mechanism of activation of amidobenzylidene ruthenium chelates – latent catalysts of olefin metathesis

S. Rogalski, P. Żak, N. Tadeuszyk, K. Pyta, P. Przybylski and C. Pietraszuk, Dalton Trans., 2017, 46, 1277 DOI: 10.1039/C6DT04290B

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