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Issue 1, 2017
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Synthesis of cyclic organic carbonates via catalytic oxidative carboxylation of olefins in flow reactors

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Abstract

Methodology for direct catalytic conversion of olefins into cyclic carbonates using peroxide and carbon dioxide under relatively mild conditions is demonstrated. The protocol utilizes packed bed flow reactors in series to couple rhenium catalyzed olefin epoxidation and aluminum catalyzed epoxide carboxylation in a single sequence.

Graphical abstract: Synthesis of cyclic organic carbonates via catalytic oxidative carboxylation of olefins in flow reactors

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Publication details

The article was received on 16 Sep 2016, accepted on 24 Nov 2016 and first published on 25 Nov 2016


Article type: Paper
DOI: 10.1039/C6CY01974A
Catal. Sci. Technol., 2017,7, 84-89

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    Synthesis of cyclic organic carbonates via catalytic oxidative carboxylation of olefins in flow reactors

    A. A. Sathe, A. M. K. Nambiar and R. M. Rioux, Catal. Sci. Technol., 2017, 7, 84
    DOI: 10.1039/C6CY01974A

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