Solar cells with PbS quantum dot sensitized TiO2–multiwalled carbon nanotube composites, sulfide-titania gel and tin sulfide coated C-fabric

Abstract

Novel approaches to boost quantum dot solar cell (QDSC) efficiencies are in demand. Herein, three strategies are used: (i) a hydrothermally synthesized TiO₂–multiwalled carbon nanotube (MWCNT) composite instead of conventional TiO₂, (ii) a counter electrode (CE) that has not been applied to QDSCs until now, namely, tin sulfide (SnS) nanoparticles (NPs) coated over a conductive carbon (C)-fabric, and (iii) a quasi-solid-state gel electrolyte composed of S²⁻, an inert polymer and TiO₂ nanoparticles as opposed to a polysulfide solution based hole transport layer. MWCNTs by virtue of their high electrical conductivity and suitably positioned Fermi level (below the conduction bands of TiO₂ and PbS) allow fast photogenerated electron injection into the external circuit, and this is confirmed by a higher efficiency of 6.3% achieved for a TiO₂–MWCNT/PbS/ZnS based (champion) cell, compared to the corresponding TiO₂/PbS/ZnS based cell (4.45%). Nanoscale current map analysis of TiO₂ and TiO₂–MWCNTs reveals the presence of narrowly spaced highly conducting domains in the latter, which equips it with an average current carrying capability greater by a few orders of magnitude. Electron transport and recombination resistances are lower and higher respectively for the TiO₂–MWCNT/PbS/ZnS cell relative to the TiO₂/PbS/ZnS cell, thus leading to a high performance cell. The efficacy of SnS/C-fabric as a CE is confirmed from the higher efficiency achieved in cells with this CE compared to the C-fabric based cells. Lower charge transfer and diffusional resistances, slower photovoltage decay, high electrical conductance and lower redox potential impart high catalytic activity to the SnS/C-fabric assembly for sulfide reduction and thus endow the TiO₂–MWCNT/PbS/ZnS cell with a high open circuit voltage (0.9 V) and a large short circuit current density (∼20 mA cm⁻²). This study attempts to unravel how simple strategies can amplify QDSC performances.