Issue 31, 2017

Geometric and electronic properties of Si-atom doped Al clusters: robustness of binary superatoms against charging

Abstract

The geometric and electronic properties of silicon-atom-doped aluminum clusters, AlnSim (n = 7–30, m = 0–2), were investigated experimentally. The size dependences of the ionization energy and electron affinity of AlnSim show that the stability of AlnSim is governed by the total number of valence electrons in the clusters, where Al and Si atoms behave as trivalent and tetravalent atoms, respectively. Together with theoretical calculations, it has been revealed that neutral Al10Si and Al12Si have a cage-like geometry with central Si atom encapsulation and closed electronic structures of superatomic orbitals (SAOs), and also that they both exhibit geometric robustness against reductive and oxidative changes as cage-like binary superatoms of Si@Al10 and Si@Al12. As well as the single-atom-doped binary superatoms, the effect of symmetry lowering was examined by doping a second Si atom toward the electron SAO closing of 2P SAO, forming Al11Si2. The corresponding anion and cation clusters keep their geometry of the neutral intact, and the ionization energy is low compared to others, showing that Al11Si2 is characterized to be, Si@Al11Si as an alkaline-like binary superatom. For Al21Si2, a face-sharing bi-icosahedral structure was identified to be the most stable as dimeric superatom clusters.

Graphical abstract: Geometric and electronic properties of Si-atom doped Al clusters: robustness of binary superatoms against charging

Supplementary files

Article information

Article type
Paper
Submitted
21 May 2017
Accepted
09 Jul 2017
First published
10 Jul 2017

Phys. Chem. Chem. Phys., 2017,19, 20401-20411

Geometric and electronic properties of Si-atom doped Al clusters: robustness of binary superatoms against charging

M. Akutsu, K. Koyasu, J. Atobe, K. Miyajima, M. Mitsui, H. Tsunoyama and A. Nakajima, Phys. Chem. Chem. Phys., 2017, 19, 20401 DOI: 10.1039/C7CP03409A

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