Achiral aromatic solvent-induced assembly of 3-D homochiral porous 3d–4f heterometallic-organic frameworks based on isonicotinic acid

Abstract

Via induction of achiral aromatic solvents, two 3-D monochiral 3d–4f MOFs (1 and 2) from the ligand HIN without any chiral auxiliary are uncommonly constructed. The results show that the homochiral compounds 1 and 2 are enantiopure rather than exhibiting enantiomeric excess. Obviously, this work has brought major synthetic advancement in homochiral framework materials of great significance.