Pd(0) loaded Zn2(azoBDC)2(dabco) as a heterogeneous catalyst

Ke Xie; Yingdian He; Qinghu Zhao; Jin Shang; Qinfen Gu; Greg G. Qiao; Paul A. Webley

doi:10.1039/C6CE02447E

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Pd(0) loaded Zn₂(azoBDC)₂(dabco) as a heterogeneous catalyst†

Ke Xie,

‡^a Yingdian He,‡^a Qinghu Zhao,^a Jin Shang,^b Qinfen Gu,^c Greg G. Qiao

^a and Paul A. Webley*^a

Author affiliations

* Corresponding authors

^a Department of Chemical and Biomolecular Engineering, The University of Melbourne, Melbourne, VIC 3010, Australia
E-mail: paul.webley@unimelb.edu.au

^b School of Energy and Environment, University of Hong Kong, Kowloon, Hong Kong

^c Australian Synchrotron Company Ltd, Melbourne, VIC 3168, Australia

Abstract

We report a novel Pd(0) loaded metal–organic framework (MOF) catalyst, namely Pd@Zn₂(azoBDC)₂(dabco). The efficient catalytic activity and good recyclability of the heterogeneous catalyst carrier are demonstrated through the probe reduction reaction of 4-nitrophenol (NP) to 4-aminophenol (AP) by sodium borohydride (NaBH₄).

This article is part of the themed collection: Metal-Organic Framework Catalysis

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Article information

DOI: https://doi.org/10.1039/C6CE02447E
Article type: Paper
Submitted: 24 Nov 2016
Accepted: 10 Jan 2017
First published: 10 Jan 2017

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CrystEngComm, 2017,19, 4182-4186

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Pd(0) loaded Zn₂(azoBDC)₂(dabco) as a heterogeneous catalyst

K. Xie, Y. He, Q. Zhao, J. Shang, Q. Gu, G. G. Qiao and P. A. Webley, CrystEngComm, 2017, 19, 4182 DOI: 10.1039/C6CE02447E

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