Issue 91, 2017

Photoinduced, copper-catalyzed three components cyanofluoroalkylation of alkenes with fluoroalkyl iodides as fluoroalkylation reagents

Abstract

In the past few years, Ru and Ir catalyzed photoredox radical coupling reactions have been widely applied in organic synthesis. In contrast, the applications of Cu catalysts in photoredox organic transformations were limited. We here report the first example of photoinduced, Cu-catalyzed three component cyanofluoroalkylation of alkenes by directly using fluoroalkyl iodides as fluoroalkylation reagents.

Graphical abstract: Photoinduced, copper-catalyzed three components cyanofluoroalkylation of alkenes with fluoroalkyl iodides as fluoroalkylation reagents

Supplementary files

Article information

Article type
Communication
Submitted
12 Sep 2017
Accepted
25 Oct 2017
First published
02 Nov 2017

Chem. Commun., 2017,53, 12317-12320

Photoinduced, copper-catalyzed three components cyanofluoroalkylation of alkenes with fluoroalkyl iodides as fluoroalkylation reagents

Q. Guo, M. Wang, Y. Wang, Z. Xu and R. Wang, Chem. Commun., 2017, 53, 12317 DOI: 10.1039/C7CC07128K

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