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Issue 89, 2017
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Catalyst free annulative thioboration of unfunctionalized olefins

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Abstract

A direct and catalyst-free annulative thioboration of unfunctionalized olefins has been developed. In the presence of BCl3 as the sole boron source, the boryl group and thiol group are added to the C–C double bonds simultaneously. The boronic acids obtained can be protected to form synthetically ubiquitous pinacol boronate esters.

Graphical abstract: Catalyst free annulative thioboration of unfunctionalized olefins

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Publication details

The article was received on 30 Aug 2017, accepted on 17 Oct 2017 and first published on 17 Oct 2017


Article type: Communication
DOI: 10.1039/C7CC06800J
Chem. Commun., 2017,53, 12092-12095

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    Catalyst free annulative thioboration of unfunctionalized olefins

    Z. Yang, C. Yang, S. Chen, X. Chen, L. Zhang and H. Ren, Chem. Commun., 2017, 53, 12092
    DOI: 10.1039/C7CC06800J

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