Issue 73, 2017
From the journal:

Chemical Communications

Tandem trifluoromethylthiolation/aryl migration of aryl alkynoates to trifluoromethylthiolated alkenes†

Huan Li,a   Shuai Liu,a   Yangen Huang, ORCID logo a   Xiu-Hua Xub  and  Feng-Ling Qing ORCID logo *ab  

* Corresponding authors

a College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, 2999 North Renmin Lu, Shanghai 201620, China

b Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, 345 Lingling Lu, Shanghai 200032, China
E-mail: flq@mail.sioc.ac.cn

Abstract

A trifluoromethylthiolation initiated aryl migration of aryl alkynoates was disclosed. This protocol employs AgSCF3 as the SCF3 source and MeCN as both the solvent and the hydrogen source. This provides a new access to trifluoromethylthiolated alkenes from readily available substrates and reagents.

Graphical abstract: Tandem trifluoromethylthiolation/aryl migration of aryl alkynoates to trifluoromethylthiolated alkenes

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Article information

DOI
https://doi.org/10.1039/C7CC06232J
Article type
Communication
Submitted
10 Aug 2017
Accepted
22 Aug 2017
First published
22 Aug 2017

Chem. Commun., 2017,53, 10136-10139

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Tandem trifluoromethylthiolation/aryl migration of aryl alkynoates to trifluoromethylthiolated alkenes

H. Li, S. Liu, Y. Huang, X. Xu and F. Qing, Chem. Commun., 2017, 53, 10136 DOI: 10.1039/C7CC06232J

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