The effect of centred versus offset interpenetration on C2H2 sorption in hybrid ultramicroporous materials

Alankriti Bajpai; Daniel O'Nolan; David G. Madden; Kai-Jie Chen; Tony Pham; Amrit Kumar; Matteo Lusi; John J. Perry; Brian Space; Michael J. Zaworotko

doi:10.1039/C7CC05882A

The effect of centred versus offset interpenetration on C₂H₂ sorption in hybrid ultramicroporous materials†

Alankriti Bajpai,

‡^a Daniel O'Nolan,

‡^a David G. Madden,

‡^a Kai-Jie Chen,

^a Tony Pham,

^b Amrit Kumar,

^a Matteo Lusi,

^a John J. Perry, IV,

^a Brian Space

^b and Michael J. Zaworotko

*^a

Author affiliations

* Corresponding authors

^a Department of Chemical Sciences and Bernal Institute, University of Limerick, Republic of Ireland
E-mail: xtal@ul.ie

^b Department of Chemistry, University of South Florida, 4202 East Fowler Avenue, Tampa, Florida, USA

Abstract

Fine-tuning of hybrid ultramicroporous materials (HUMs) can significantly impact their gas sorption performance. This study reveals that offset interpenetration can be antagonistic with respect to C₂H₂ separation from C₂H₂/C₂H₄ gas mixtures.

Chemical Communications

The effect of centred versus offset interpenetration on C₂H₂ sorption in hybrid ultramicroporous materials†

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The effect of centred versus offset interpenetration on C₂H₂ sorption in hybrid ultramicroporous materials

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