Issue 66, 2017

POSS solid solutions exhibiting orientationally disordered phase transitions

Abstract

Examples of solid solution behavior for molecular crystals are limited, due to difficulty in designing a crystalline mixture of different molecules. Here, we found that a mixture of two different monofunctionalized heptaisobutyl-substituted octasilsesquioxanes formed solid solutions showing a single phase-transition temperature, which exhibited orientationally disordered (OD) phases.

Graphical abstract: POSS solid solutions exhibiting orientationally disordered phase transitions

Supplementary files

Article information

Article type
Communication
Submitted
08 Jun 2017
Accepted
24 Jul 2017
First published
24 Jul 2017

Chem. Commun., 2017,53, 9273-9276

POSS solid solutions exhibiting orientationally disordered phase transitions

S. Morimoto, H. Imoto and K. Naka, Chem. Commun., 2017, 53, 9273 DOI: 10.1039/C7CC04443G

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