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Issue 41, 2017
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Access to cyclic gem-difluoroacyl scaffolds via electrochemical and visible light photocatalytic radical tandem cyclization of heteroaryl chlorodifluoromethyl ketones

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Abstract

A variety of unprecedented scaffolds containing a difluoroacyl moiety were obtained in moderate to good yields, with excellent diastereoselectivity, via electrochemical or photochemical activation of difluoroacyl heteroaryles with a series of olefinic substrates.

Graphical abstract: Access to cyclic gem-difluoroacyl scaffolds via electrochemical and visible light photocatalytic radical tandem cyclization of heteroaryl chlorodifluoromethyl ketones

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Publication details

The article was received on 18 Apr 2017, accepted on 02 May 2017 and first published on 02 May 2017


Article type: Communication
DOI: 10.1039/C7CC02979A
Citation: Chem. Commun., 2017,53, 5653-5656
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    Access to cyclic gem-difluoroacyl scaffolds via electrochemical and visible light photocatalytic radical tandem cyclization of heteroaryl chlorodifluoromethyl ketones

    C. Adouama, R. Keyrouz, G. Pilet, C. Monnereau, D. Gueyrard, T. Noël and M. Médebielle, Chem. Commun., 2017, 53, 5653
    DOI: 10.1039/C7CC02979A

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