The first synthesis of Bi self-doped Bi2MoO6–Bi2Mo3O12 composites and their excellent photocatalytic performance for selective oxidation of aromatic alkanes under visible light irradiation

Lu-Na Song; Lang Chen; Jie He; Peng Chen; Huang-Kai Zeng; Chak-Tong Au; Shuang-Feng Yin

doi:10.1039/C7CC02890C

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The first synthesis of Bi self-doped Bi₂MoO₆–Bi₂Mo₃O₁₂ composites and their excellent photocatalytic performance for selective oxidation of aromatic alkanes under visible light irradiation†

Lu-Na Song,‡^a Lang Chen,‡^a Jie He,^a Peng Chen,^a Huang-Kai Zeng,^a Chak-Tong Au^b and Shuang-Feng Yin

*^a

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* Corresponding authors

^a State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, Hunan, People's Republic of China
E-mail: sf_yin@hnu.edu.cn
Fax: +86-731-88821171

^b College of Chemistry and Chemical Engineering, Hunan Institute of Engineering, Xiangtan 411104, Hunan, China

Abstract

We report the synthesis of Bi self-doped Bi₂MoO₆–Bi₂Mo₃O₁₂ composites with heterostructures by a one-step method using Bi_3.64Mo_0.36O_6.55 as precursor. Among them, Bi_2.1MoO₆–Bi_2.1Mo₃O₁₂ shows excellent selectivity as well as recyclability in the oxidation of aromatic alkanes to aldehydes under visible light irradiation.

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Article information

DOI: https://doi.org/10.1039/C7CC02890C
Article type: Communication
Submitted: 14 Apr 2017
Accepted: 24 May 2017
First published: 24 May 2017

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Chem. Commun., 2017,53, 6480-6483

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The first synthesis of Bi self-doped Bi₂MoO₆–Bi₂Mo₃O₁₂ composites and their excellent photocatalytic performance for selective oxidation of aromatic alkanes under visible light irradiation

L. Song, L. Chen, J. He, P. Chen, H. Zeng, C. Au and S. Yin, Chem. Commun., 2017, 53, 6480 DOI: 10.1039/C7CC02890C

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