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Issue 41, 2017
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Confinement effects of a crystalline sponge on ferrocene and ferrocene carboxaldehyde

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Abstract

The pivotal role of π⋯π interactions in the inclusion behaviour of a series of organometallic sandwich compounds is studied through single-crystal X-ray diffraction. The confinement effects of a crystalline sponge host are investigated where, notably, we observe an enhanced rotation of the ligand ring once encapsulated by the nanoporous framework, as evidenced by SSNMR experiments.

Graphical abstract: Confinement effects of a crystalline sponge on ferrocene and ferrocene carboxaldehyde

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Publication details

The article was received on 30 Mar 2017, accepted on 02 May 2017 and first published on 02 May 2017


Article type: Communication
DOI: 10.1039/C7CC02470C
Citation: Chem. Commun., 2017,53, 5645-5648
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    Confinement effects of a crystalline sponge on ferrocene and ferrocene carboxaldehyde

    G. Brunet, D. A. Safin, K. Robeyns, G. A. Facey, I. Korobkov, Y. Filinchuk and M. Murugesu, Chem. Commun., 2017, 53, 5645
    DOI: 10.1039/C7CC02470C

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