Using a new multinucleating ligand featuring two dipyridyl alkoxide moieties and a carboxylate moiety, low symmetry tetranuclear complexes 1-M (M = Mn, Fe, and Co) have been synthesized. Complex 1-Mn was used as a precursor for the synthesis of a pentanuclear CaMn4O2 cluster (3) with the same metal stoichiometry as the biological OEC.
H. B. Lee, E. Y. Tsui and T. Agapie, Chem. Commun., 2017, 53, 6832 DOI: 10.1039/C7CC02313H
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