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Issue 30, 2017
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A family of ‘windmill’-like {Cu6Ln12} complexes exhibiting single-molecule magnetism behavior and large magnetic entropy changes

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Abstract

A family of nanosized {Cu6Ln12} clusters with a ‘windmill’-like topology was prepared from the employment of 2,6-diacetylpyridine dioxime, in conjunction with bridging N3, in 3d/4f-metal chemistry; the octadecanuclear compounds exhibit single-molecule magnetism behavior and large magnetic entropy changes, depending on the 4f-metal ion present.

Graphical abstract: A family of ‘windmill’-like {Cu6Ln12} complexes exhibiting single-molecule magnetism behavior and large magnetic entropy changes

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Publication details

The article was received on 21 Feb 2017, accepted on 23 Mar 2017 and first published on 24 Mar 2017


Article type: Communication
DOI: 10.1039/C7CC01382E
Citation: Chem. Commun., 2017,53, 4266-4269

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    A family of ‘windmill’-like {Cu6Ln12} complexes exhibiting single-molecule magnetism behavior and large magnetic entropy changes

    D. I. Alexandropoulos, K. M. Poole, L. Cunha-Silva, J. Ahmad Sheikh, W. Wernsdorfer, G. Christou and T. C. Stamatatos, Chem. Commun., 2017, 53, 4266
    DOI: 10.1039/C7CC01382E

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