Issue 10, 2017
From the journal:

Chemical Communications

Taco complex-templated highly regio- and stereo-selective photodimerization of a coumarin-containing crown ether†

Peifa Wei,a   Haoze Wang,a   Kecheng Jie ORCID logo a  and  Feihe Huang ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Chemical Engineering, Center for Chemistry of High-Performance & Novel Materials, Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China
E-mail: fhuang@zju.edu.cn
Fax: +86-571-8795-3189
Tel: +86-571-8795-3189

Abstract

Preorientation of the terminal coumarins of a crown ether with the assistance of taco-type host–guest complex formation promotes regio- and stereo-selectivity of coumarin photodimerization to give only the syn head-to-tail coumarin isomer.

Graphical abstract: Taco complex-templated highly regio- and stereo-selective photodimerization of a coumarin-containing crown ether

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Article information

DOI
https://doi.org/10.1039/C6CC10089A
Article type
Communication
Submitted
20 Dec 2016
Accepted
06 Jan 2017
First published
06 Jan 2017

Chem. Commun., 2017,53, 1688-1691

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Taco complex-templated highly regio- and stereo-selective photodimerization of a coumarin-containing crown ether

P. Wei, H. Wang, K. Jie and F. Huang, Chem. Commun., 2017, 53, 1688 DOI: 10.1039/C6CC10089A

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