Issue 21, 2017
From the journal:

Chemical Communications

Evaporation rate-based selection of supramolecular chirality†

Shingo Hattori,a   Stefaan Vandendriessche,b   Guy Koeckelberghs,c   Thierry Verbiest*b  and  Kazuyuki Ishii ORCID logo *a  

* Corresponding authors

a Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505, Japan
E-mail: k-ishii@iis.u-tokyo.ac.jp

b Molecular Imaging and Photonics, KU Leuven, Celestijnenlaan 200D – box 2425, 3001 Heverlee, Belgium

c Polymer Chemistry and Materials, KU Leuven, Celestijnenlaan 200F – box 2404, 3001 Heverlee, Belgium

Abstract

We demonstrate the evaporation rate-based selection of supramolecular chirality for the first time. P-type aggregates prepared by fast evaporation, and M-type aggregates prepared by slow evaporation are kinetic and thermodynamic products under dynamic reaction conditions, respectively. These findings provide a novel solution reaction chemistry under the dynamic reaction conditions.

Graphical abstract: Evaporation rate-based selection of supramolecular chirality

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C6CC09842H
Article type
Communication
Submitted
11 Dec 2016
Accepted
21 Feb 2017
First published
21 Feb 2017

Chem. Commun., 2017,53, 3066-3069

Permissions

Request permissions

Evaporation rate-based selection of supramolecular chirality

S. Hattori, S. Vandendriessche, G. Koeckelberghs, T. Verbiest and K. Ishii, Chem. Commun., 2017, 53, 3066 DOI: 10.1039/C6CC09842H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements