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Issue 16, 2017
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Silver(i)-promoted insertion into X–H (X = Si, Sn, and Ge) bonds with N-nosylhydrazones

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Abstract

Silver(I)-promoted carbene insertion into X–H (X = Si, Sn, and Ge) bonds has been realized by using unstable diazo compounds, which are generated in situ from N-nosylhydrazones as carbene precursors. The reaction tolerates a wide range of functional groups and delivers a number of valuable silicon-containing compounds in very high yields (up to 96%). Moreover, organostannanes and organogermanes were as well effectively obtained in very good yields under optimal conditions.

Graphical abstract: Silver(i)-promoted insertion into X–H (X = Si, Sn, and Ge) bonds with N-nosylhydrazones

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Supplementary files

Article information


Submitted
05 Dec 2016
Accepted
02 Feb 2017
First published
10 Feb 2017

Chem. Commun., 2017,53, 2503-2506
Article type
Communication

Silver(I)-promoted insertion into X–H (X = Si, Sn, and Ge) bonds with N-nosylhydrazones

Z. Liu, Q. Li, Y. Yang and X. Bi, Chem. Commun., 2017, 53, 2503
DOI: 10.1039/C6CC09650F

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