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Issue 14, 2017
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Electronic perturbation of supramolecular conjugates of porphyrins and phthalocyanines

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Abstract

The redox potential of a supramolecular porphyrin–phthalocyanine heterodimer was perturbed by the stacking of an extra metalloporphyrin to the phthalocyanine. This stacking gave rise to π–π and electrostatic interactions between the tetracationic dimer and the tetraanionic metalloporphyrin, with a Au(III) metalloporphyrin exhibiting a larger effect than Cu(II) and Pd(II) complexes among square planar complexes.

Graphical abstract: Electronic perturbation of supramolecular conjugates of porphyrins and phthalocyanines

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Publication details

The article was received on 02 Dec 2016, accepted on 17 Jan 2017 and first published on 25 Jan 2017


Article type: Communication
DOI: 10.1039/C6CC09590A
Citation: Chem. Commun., 2017,53, 2230-2232
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    Electronic perturbation of supramolecular conjugates of porphyrins and phthalocyanines

    N. Mihara, Y. Yamada, S. Akine, K. Sugimoto and K. Tanaka, Chem. Commun., 2017, 53, 2230
    DOI: 10.1039/C6CC09590A

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