Issue 6, 2017
From the journal:

Chemical Communications

Transformation of nortricyclane type cage compounds P4S3, P4Se3 and As4S3 by [Cp′′2Zr(CO)2]†

A. E. Seitz,a   V. Heinl,a   A. Y. Timoshkinb  and  M. Scheer ORCID logo *a  

* Corresponding authors

a Institute of Inorganic Chemistry, University of Regensburg, Universitätsstr. 31, 93040 Regensburg, Germany
E-mail: manfred.scheer@ur.de

b Institute of Chemistry, St. Petersburg State University, Universitetskaya nab. 7/9, St. Petersburg, Russia

Abstract

The complex [Cp′′2Zr(CO)2] (Cp′′ = C5H3tBu2) was used to transform the nortricyclane type cage compounds E4Q3 (E = P, Q = S, Se; E = As, Q = S) resulting in unprecedented complexes [(Cp′′2Zr)2(μ,η1:1:1:1-E2Q4)] possessing bridging ligands that represent the anions of the so far unknown tetrachalcogenohypodiphosphorous acid (HQ)2PP(QH)2 and tetrathiohypodiarsenous acid (HS)2AsAs(SH)2, respectively.

Graphical abstract: Transformation of nortricyclane type cage compounds P4S3, P4Se3 and As4S3 by [Cp′′2Zr(CO)2]

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Article information

DOI
https://doi.org/10.1039/C6CC09427A
Article type
Communication
Submitted
25 Nov 2016
Accepted
20 Dec 2016
First published
20 Dec 2016

Chem. Commun., 2017,53, 1172-1175

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Transformation of nortricyclane type cage compounds P4S3, P4Se3 and As4S3 by [Cp′′2Zr(CO)2]

A. E. Seitz, V. Heinl, A. Y. Timoshkin and M. Scheer, Chem. Commun., 2017, 53, 1172 DOI: 10.1039/C6CC09427A

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