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Issue 4, 2017
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Homoleptic organolanthanide compounds supported by the bis(dimethylsilyl)benzyl ligand

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Abstract

A β-SiH functionalized benzyl anion [C(SiHMe2)2Ph] is obtained by deprotonation of HC(SiHMe2)2Ph with KCH2Ph or by reaction of KOtBu and (Me2HSi)3CPh; LnI3(THF)n and three equivalents of this carbanion combine to provide homoleptic tris(alkyl)lanthanide compounds Ln{C(SiHMe2)2Ph}3 (Ln = La, Ce, Pr, Nd) containing secondary metal–ligand interactions.

Graphical abstract: Homoleptic organolanthanide compounds supported by the bis(dimethylsilyl)benzyl ligand

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Publication details

The article was received on 21 Nov 2016, accepted on 12 Dec 2016 and first published on 19 Dec 2016


Article type: Communication
DOI: 10.1039/C6CC09304C
Citation: Chem. Commun., 2017,53, 716-719
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    Homoleptic organolanthanide compounds supported by the bis(dimethylsilyl)benzyl ligand

    K. C. Boteju, A. Ellern and A. D. Sadow, Chem. Commun., 2017, 53, 716
    DOI: 10.1039/C6CC09304C

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