Issue 4, 2017
From the journal:

Chemical Communications

High oxidation state bromocarbyne complexes†

Anthony F. Hill ORCID logo *a  and  Richard Y. Kong ORCID logo a  

* Corresponding authors

a Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory, Australia
E-mail: a.hill@anu.edu.au

Abstract

Bromination of the carbyne complexes [W([triple bond, length as m-dash]CR)Br(CO)2(dcpe)] (R = Ph, SiPh3; dcpe = 1,2-bis(dicyclohexylphosphino)ethane) provides high oxidation state derivatives [W([triple bond, length as m-dash]CPh)Br3(dcpe)] and [W([triple bond, length as m-dash]CBr)Br3(dcpe)], the latter via an unprecedented bromodesilylation process.

Graphical abstract: High oxidation state bromocarbyne complexes

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Article information

DOI
https://doi.org/10.1039/C6CC08946A
Article type
Communication
Submitted
09 Nov 2016
Accepted
10 Dec 2016
First published
12 Dec 2016
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2017,53, 759-762

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High oxidation state bromocarbyne complexes

A. F. Hill and R. Y. Kong, Chem. Commun., 2017, 53, 759 DOI: 10.1039/C6CC08946A

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