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Issue 2, 2017
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Reduced thione ligation is preferred over neutral phosphine ligation in diiron biomimics regarding electronic functionality: a spectroscopic and computational investigation

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Abstract

Sulfur containing ligands with a thiolate-thiyl radical character are much superior than phosphine ligands in the active site modeling of [FeFe]hydrogenase regarding electronic functionality on charge communication and modulation of the electronic structure of the catalytic metal center.

Graphical abstract: Reduced thione ligation is preferred over neutral phosphine ligation in diiron biomimics regarding electronic functionality: a spectroscopic and computational investigation

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Publication details

The article was received on 05 Oct 2016, accepted on 29 Nov 2016 and first published on 29 Nov 2016


Article type: Communication
DOI: 10.1039/C6CC08042A
Chem. Commun., 2017,53, 332-335

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    Reduced thione ligation is preferred over neutral phosphine ligation in diiron biomimics regarding electronic functionality: a spectroscopic and computational investigation

    T. Yen, Z. He, G. Lee, M. Tseng, Y. Shen, T. Tseng, W. Liaw and M. Chiang, Chem. Commun., 2017, 53, 332
    DOI: 10.1039/C6CC08042A

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