Issue 3, 2017
From the journal:

Chemical Communications

A redox active switch for lanthanide luminescence in phenolate complexes†

J. K. Molloy,ab   O. Jarjayes,a   C. Philouze,a   L. Fedele,b   D. Imbert ORCID logo *b  and  F. Thomas*a  

* Corresponding authors

a Département de Chimie Moléculaire, Chimie Inorganique Redox (CIRE), UMR CNRS 5250, Université Grenoble-Alpes, B. P. 53, 38041 Grenoble Cedex 9, France
E-mail: fabrice.thomas@univ-grenoble-alpes.fr

b Laboratoire de Reconnaissance Ionique et Chimie de Coordination SCIB, UMR-E3 CEA-UJF, INAC, CEA-Grenoble, 17 rue des Martyrs, 38054 Grenoble Cedex 09, France

Abstract

The reversible oxidation of coordinated phenolates into phenoxyl radicals results in a dramatic quenching (>95%) of the luminescence of the f metal ion.

Graphical abstract: A redox active switch for lanthanide luminescence in phenolate complexes

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Article information

DOI
https://doi.org/10.1039/C6CC07942C
Article type
Communication
Submitted
30 Sep 2016
Accepted
05 Dec 2016
First published
05 Dec 2016

Chem. Commun., 2017,53, 605-608

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A redox active switch for lanthanide luminescence in phenolate complexes

J. K. Molloy, O. Jarjayes, C. Philouze, L. Fedele, D. Imbert and F. Thomas, Chem. Commun., 2017, 53, 605 DOI: 10.1039/C6CC07942C

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