Issue 3, 2017
From the journal:

Chemical Communications

A direct cross-coupling reaction of electron-deficient alkenes using an oxidizing directing group†

Chunbing Yu,a   Feifei Li,a   Jian Zhang ORCID logo *a  and  Guofu Zhong*a  

* Corresponding authors

a College of Materials, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 310036, China
E-mail: zhangjian@hznu.edu.cn, zgf@hznu.edu.cn

Abstract

An oxidant-free cross-coupling reaction of electron-deficient alkenes using an inexpensive ruthenium catalyst is reported. With the assistance of the oxidizing directing group CONH(OMe), this protocol provides a mild, straightforward and efficient method for the preparation of valuable 1,3-butadiene skeletons with excellent Z,E selectivities.

Graphical abstract: A direct cross-coupling reaction of electron-deficient alkenes using an oxidizing directing group

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Article information

DOI
https://doi.org/10.1039/C6CC07064G
Article type
Communication
Submitted
29 Aug 2016
Accepted
05 Dec 2016
First published
06 Dec 2016

Chem. Commun., 2017,53, 533-536

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A direct cross-coupling reaction of electron-deficient alkenes using an oxidizing directing group

C. Yu, F. Li, J. Zhang and G. Zhong, Chem. Commun., 2017, 53, 533 DOI: 10.1039/C6CC07064G

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