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Issue 2, 2016
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Ultrathin nanosheets of CrSiTe3: a semiconducting two-dimensional ferromagnetic material

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Abstract

Finite range ferromagnetism and antiferromagnetism in two-dimensional (2D) systems within an isotropic Heisenberg model at non-zero temperature were originally proposed to be impossible. However, recent theoretical studies using an Ising model have shown that 2D magnetic crystals can exhibit magnetism. Experimental verification of existing 2D magnetic crystals in this system has remained exploratory. In this work we exfoliated CrSiTe3, a bulk ferromagnetic semiconductor, to mono- and few-layer 2D crystals onto a Si/SiO2 substrate. Raman spectra indicate good stability and high quality of the exfoliated flakes, consistent with the computed phonon spectra of 2D CrSiTe3, giving strong evidence for the existence of 2D CrSiTe3 crystals. When the thickness of the CrSiTe3 crystals is reduced to a few layers, we observed a clear change in resistivity at 80–120 K, consistent with theoretical calculations of the Curie temperature (Tc) of ∼80 K for the magnetic ordering of 2D CrSiTe3 crystals. The ferromagnetic mono- and few-layer 2D CrSiTe3 indicated here should enable numerous applications in nano-spintronics.

Graphical abstract: Ultrathin nanosheets of CrSiTe3: a semiconducting two-dimensional ferromagnetic material

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Supplementary files

Article information


Submitted
22 Oct 2015
Accepted
25 Nov 2015
First published
27 Nov 2015

J. Mater. Chem. C, 2016,4, 315-322
Article type
Paper
Author version available

Ultrathin nanosheets of CrSiTe3: a semiconducting two-dimensional ferromagnetic material

M. Lin, H. L. Zhuang, J. Yan, T. Z. Ward, A. A. Puretzky, C. M. Rouleau, Z. Gai, L. Liang, V. Meunier, B. G. Sumpter, P. Ganesh, P. R. C. Kent, D. B. Geohegan, D. G. Mandrus and K. Xiao, J. Mater. Chem. C, 2016, 4, 315
DOI: 10.1039/C5TC03463A

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