Issue 30, 2016
From the journal:

Journal of Materials Chemistry A

Rational synthesis of a novel 3,3,5-c polyhedral metal–organic framework with high thermal stability and hydrogen storage capability†

Jianqiang Liu,*a   Guoliang Liu,bc   Chuying Gu,a   Weicong Liu,a   Jingwen Xu,a   Baohong Lia  and  Wenjing Wang*bc  

* Corresponding authors

a School of Pharmacy, Guangdong Medical University, Dongguan, China
E-mail: jianqiangliu2010@126.com

b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China
E-mail: wjwang@fjirsm.ac.cn

c University of the Chinese Academy of Sciences, Beijing, China

Abstract

By using a functionalized ligand strategy, a novel (3,3,5)-c polyhedron-based metal–organic framework (GDMU-2) with high thermal stability has been constructed. GDMU-2 shows a high H2 uptake of 240.7 cm3 g−1 (2.16 wt%) at 77 K and 1 bar, and also exhibits a good selective adsorption of CO2 over N2 and CH4.

Graphical abstract: Rational synthesis of a novel 3,3,5-c polyhedral metal–organic framework with high thermal stability and hydrogen storage capability

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Article information

DOI
https://doi.org/10.1039/C6TA03675A
Article type
Communication
Submitted
03 May 2016
Accepted
06 Jul 2016
First published
07 Jul 2016

J. Mater. Chem. A, 2016,4, 11630-11634

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Rational synthesis of a novel 3,3,5-c polyhedral metal–organic framework with high thermal stability and hydrogen storage capability

J. Liu, G. Liu, C. Gu, W. Liu, J. Xu, B. Li and W. Wang, J. Mater. Chem. A, 2016, 4, 11630 DOI: 10.1039/C6TA03675A

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