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Issue 20, 2016
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Hollow nanoporous covalent triazine frameworks via acid vapor-assisted solid phase synthesis for enhanced visible light photoactivity

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Abstract

Herein, we report a novel trifluoromethanesulfonic acid vapor-assisted solid phase synthetic method to construct nanoporous covalent triazine frameworks with highly ordered hollow interconnected pores under mild reaction conditions. This unique solid state synthetic route allows not only the avoidance of undesired side reactions caused by traditional high temperature synthesis, but also the maintaining of defined and precise optical and electronic properties of the nonporous triazine frameworks. Promising photocatalytic activity of the polytriazine networks was demonstrated in the photoreduction reaction of 4-nitrophenol into 4-aminophenol under visible light irradiation.

Graphical abstract: Hollow nanoporous covalent triazine frameworks via acid vapor-assisted solid phase synthesis for enhanced visible light photoactivity

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Supplementary files

Article information


Submitted
01 Mar 2016
Accepted
01 Apr 2016
First published
11 Apr 2016

This article is Open Access

J. Mater. Chem. A, 2016,4, 7555-7559
Article type
Communication

Hollow nanoporous covalent triazine frameworks via acid vapor-assisted solid phase synthesis for enhanced visible light photoactivity

W. Huang, Z. J. Wang, B. C. Ma, S. Ghasimi, D. Gehrig, F. Laquai, K. Landfester and K. A. I. Zhang, J. Mater. Chem. A, 2016, 4, 7555
DOI: 10.1039/C6TA01828A

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