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Issue 20, 2016
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Hollow nanoporous covalent triazine frameworks via acid vapor-assisted solid phase synthesis for enhanced visible light photoactivity

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Abstract

Herein, we report a novel trifluoromethanesulfonic acid vapor-assisted solid phase synthetic method to construct nanoporous covalent triazine frameworks with highly ordered hollow interconnected pores under mild reaction conditions. This unique solid state synthetic route allows not only the avoidance of undesired side reactions caused by traditional high temperature synthesis, but also the maintaining of defined and precise optical and electronic properties of the nonporous triazine frameworks. Promising photocatalytic activity of the polytriazine networks was demonstrated in the photoreduction reaction of 4-nitrophenol into 4-aminophenol under visible light irradiation.

Graphical abstract: Hollow nanoporous covalent triazine frameworks via acid vapor-assisted solid phase synthesis for enhanced visible light photoactivity

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Publication details

The article was received on 01 Mar 2016, accepted on 01 Apr 2016 and first published on 11 Apr 2016


Article type: Communication
DOI: 10.1039/C6TA01828A
Citation: J. Mater. Chem. A, 2016,4, 7555-7559
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    Hollow nanoporous covalent triazine frameworks via acid vapor-assisted solid phase synthesis for enhanced visible light photoactivity

    W. Huang, Z. J. Wang, B. C. Ma, S. Ghasimi, D. Gehrig, F. Laquai, K. Landfester and K. A. I. Zhang, J. Mater. Chem. A, 2016, 4, 7555
    DOI: 10.1039/C6TA01828A

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