Issue 24, 2016

Interactions of complex polymers with nanoporous substrate


With the advance of polymer synthesis, polymers that possess unique architectures such as stars or cyclic chains, and unique chemical composition distributions such as block copolymers or statistical copolymers have become frequently encountered. Characterization of these complex polymer systems drives the development of interactive chromatography where the adsorption of polymers on the porous substrate in chromatography columns is finely tuned. Liquid Chromatography at the Critical Condition (LCCC) in particular makes use of the existence of the Critical Adsorption Point (CAP) of polymers on solid surfaces and has been successfully applied to characterization of complex polymer systems. Interpretation and understanding of chromatography behaviour of complex polymers in interactive chromatography motivates theoretical/computational studies on the CAP of polymers and partitioning of these complex polymers near the CAP. This review article covers the theoretical questions encountered in chromatographic studies of complex polymers.

Graphical abstract: Interactions of complex polymers with nanoporous substrate

Article information

Article type
Review Article
30 Mar 2016
27 May 2016
First published
06 Jun 2016
This article is Open Access
Creative Commons BY license

Soft Matter, 2016,12, 5245-5256

Interactions of complex polymers with nanoporous substrate

J. D. Ziebarth and Y. Wang, Soft Matter, 2016, 12, 5245 DOI: 10.1039/C6SM00768F

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