Issue 3, 2016

Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion

Abstract

The halogenation of metallapentalyne led to the formation of metallapentalenes, which were fully characterized and studied by DFT calculations. The experimental and computational studies indicate that four resonance forms contribute to the overall structure of the metallapentalenes, and one resonance form could be viewed as the first examples of metallaiodirenium and metallabromirenium ions.

Graphical abstract: Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion

Supplementary files

Article information

Article type
Edge Article
Submitted
20 Oct 2015
Accepted
17 Nov 2015
First published
23 Nov 2015
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2016,7, 1815-1818

Halogenation of carbyne complexes: isolation of unsaturated metallaiodirenium ion and metallabromirenium ion

M. Luo, C. Zhu, L. Chen, H. Zhang and H. Xia, Chem. Sci., 2016, 7, 1815 DOI: 10.1039/C5SC03963K

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements