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Issue 3, 2016
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Surface water retardation around single-chain polymeric nanoparticles: critical for catalytic function?

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Abstract

A library of water-soluble dynamic single-chain polymeric nanoparticles (SCPN) was prepared using a controlled radical polymerisation technique followed by the introduction of functional groups, including probes at targeted positions. The combined tools of electron paramagnetic resonance (EPR) and Overhauser dynamic nuclear polarization (ODNP) reveal that these SCPNs have structural and surface hydration properties resembling that of enzymes.

Graphical abstract: Surface water retardation around single-chain polymeric nanoparticles: critical for catalytic function?

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Supplementary files

Article information


Submitted
26 Jun 2015
Accepted
08 Dec 2015
First published
08 Dec 2015

This article is Open Access
All publication charges for this article have been paid for by the Royal Society of Chemistry

Chem. Sci., 2016,7, 2011-2015
Article type
Edge Article
Author version available

Surface water retardation around single-chain polymeric nanoparticles: critical for catalytic function?

P. J. M. Stals, C. Cheng, L. van Beek, A. C. Wauters, A. R. A. Palmans, S. Han and E. W. Meijer, Chem. Sci., 2016, 7, 2011
DOI: 10.1039/C5SC02319J

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